Notes |
XRD & 1HNMR spectra, user instruction for enquiring |
Store |
25℃ under N2 atmosphere |
Packaging |
25 g, or as required in glass bottle |
Solubility |
Soluble in DMF, DMSO, et al |
Mol. Weight |
278.11 |
Appearance |
white solid |
Linear Formula |
Cl2Pb |
Purity |
99.9% |
CAS Number |
7758-95-4 |
Name(EN) |
PbCl2 |
Abstract
A novel lead coordination compound based on an extend viologen derivated ligand, [Pb4(TTVTC)Cl6(H2O)2] was successfully assembled under solvothermal condition and characterized. Single crystal structure study reveals that compound 1 is a 2D layer. Adjacent Pb2+ ions are doubly bridged by isophthalates and µ 2-Cl ions to form an infinite one dimensional (1D) ladder-like chain. The chains are further interlinked by the TTV moieties to generate a 2D layer. And hydrogen bond interaction based on C–H···Cl and C–H···O forms the supramolecular 3D structure. Additionally, Solid- state fluorescence shows that 1 emits pale green fluorescence, which can be assigned to the inter-ligand π*–π and/or π*–n transitions.