| Notes |
1HNMR spectra, user instruction for enquiring |
| Store |
25℃ under N2 atmosphere |
| Packaging |
3 g, or as required in glass bottle |
| Solubility |
Soluble in water，EtOH et al |
| Appearance |
White, beige solid |
| Purity |
99.5% |
| Linear Formula |
C4H14I2N2 |
| CAS Number |
916849-52-0
|
| Synonym |
BDADI/(BdA)I2 |
| Mol. Weight |
343.98 |
Tin-lead (Sn-Pb) alloyed perovskites with tunable bandgaps hold great potential for constructing highly efficient single-junction and tandem photovoltaic devices. However, the efficiency and stability of Sn-Pb perovskite solar cells (PSCs) are greatly hampered by severe nonradiative recombination due to the easy oxidation of Sn(II). In this work, we report the construction of mixed dimensional two-dimensional (2D) Dion—Jacobson (DJ) and three-dimensional (3D) perovskites to improve the efficiency and stability of Sn-Pb alloyed PSCs. Introducing a small amount of 1,4-butanediammonium diiodide as spacer cations of DJ perovskites into precursor, the prepared mixed dimensional Sn-Pb alloyed perovskites exhibit reduced trap-state density due to the passivation of 2D DJ perovskites. As a result, nonradiative charge recombination is greatly suppressed. The prepared Sn-Pb alloyed PSCs based on 2D-DJ/3D heterojunction deliver a power conversion efficiency of 19.02% with an impressive fill factor of 80%. As well, improved device stability is realized due to the presence of DJ perovskites which serves as a protection barrier against oxidation and water invasion. [Figure not available: see fulltext.]
